Eur. Phys. J. E (2008) 25: 91-101
https://doi.org/10.1140/epje/i2007-10267-3

Regular Article

Non-linear rheology of lamellar liquid crystals

¹ Department of Chemistry, National Taiwan University, 106, Taipei, Taiwan
² Department of Physics and Center for Complex Systems, National Central University, 320, Jung-li, Taiwan
³ Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 192-0397, Tokyo, Japan

^* e-mail: cydlu@ntu.edu.tw
^** e-mail: komura@tmu.ac.jp

Received: 1 August 2007
Accepted: 9 January 2008
Published online: 29 February 2008

Abstract

We measure the non-linear relation between the shear stress and shear rate in the lyotropic lamellar phase of C₁₂E₅ /water system. The measured shear thinning exponent changes with the surfactant concentration. A simple rheology theory of a lamellar or smectic phase is proposed with a prediction ∼ σ^3/2 , where is the shear rate and σ is the shear stress. We consider that the shear flow passed through the defect structure causes the main dissipation. As the defect line density varies with the shear rate, the shear thinning arises. The defect density is estimated by the dynamic balance between the production and annihilation processes. The defect production is caused by the shear-induced layer undulation instability. The annihilation occurs through the shear-induced defect collision process. Further flow visualization experiment shows that the defect texture correlates strongly with the shear thinning exponent.