https://doi.org/10.1140/epje/i2015-15026-3
Regular Article
Contribution to the benchmark for ternary mixtures: Measurement of diffusion and Soret coefficients of ternary system tetrahydronaphtalene-isobutylbenzene-n-dodecane with mass fractions 80-10-10 at 25 °C
Microgravity Research Center, Université libre de Bruxelles, Dept. Chemical Physics, Avenue F. D. Roosevelt, B-1050, Brussels, Belgium
* e-mail: qgaland@ulb.ac.be
Received:
16
July
2014
Revised:
19
November
2014
Accepted:
3
February
2015
Published online:
27
April
2015
This paper provides the molecular diffusion and Soret coefficients of the ternary system 1,2,3,4-tetrahydronaphtalene, isobutylbenzene, n -dodecane system at mass fractions 0.8-0.1-0.1 and temperature 25 °C for implementation into the benchmark presented in this topical issue. The Soret coefficients are determined by digital interferometry using the data of DSC-DCMIX microgravity experiment. The method used takes into account the influence of the thermal field on the Soret separations and the selection of the image processing techniques results in reproducible Soret coefficients.The diffusion coefficients are obtained by the Open Ended Capillary technique The fitting of the data collected through a set of two complementary experimental runs allows retrieving the four Fickian diffusion coefficients.
Key words: Topical Issue: Thermal non-equilibrium phenomena in multi-component fluids
© EDP Sciences, SIF, Springer-Verlag Berlin Heidelberg, 2015