https://doi.org/10.1140/epje/i2007-10206-4
Regular Article
Simulation study of random sequential adsorption of mixtures on a triangular lattice
1
Faculty of Engineering, Trg D. Obradovića 6, 21000, Novi Sad, Serbia
2
Institute of Physics, P.O. Box 68, Zemun 11080, Belgrade, Serbia
* e-mail: vrhovac@phy.bg.ac.yu;
Received:
12
June
2007
Accepted:
9
July
2007
Published online:
3
September
2007
Random sequential adsorption of binary mixtures of extended objects on a two-dimensional triangular lattice is studied numerically by means of Monte Carlo simulations. The depositing objects are formed by self-avoiding random walks on the lattice. We concentrate here on the influence of the symmetry properties of the shapes on the kinetics of the deposition processes in two-component mixtures. Approach to the jamming limit in the case of mixtures is found to be exponential, of the form: θ(t) ∼ θjam - Δθ exp(- t/σ), and the values of the parameter σ are determined by the order of symmetry of the less symmetric object in the mixture. Depending on the local geometry of the objects making the mixture, jamming coverage of a mixture can be either greater than both single-component jamming coverages or it can be in between these values. Results of the simulations for various fractional concentrations of the objects in the mixture are also presented.
PACS: 68.43.Mn Adsorption/desorption kinetics – / 05.10.Ln Monte Carlo methods – / 02.50.-r Probability theory, stochastic processes, and statistics – / 05.70.Ln Nonequilibrium and irreversible thermodynamics –
© EDP Sciences, Società Italiana di Fisica and Springer-Verlag, 2007