DOI: 10.1140/epje/e2003-00003-4
pH effects in the formation of interpolymer complexes between poly(N-vinylpyrrolidone) and poly(acrylic acid) in aqueous solutions
Z.S. Nurkeeva, G.A. Mun, V.V. Khutoryanskiy, A.B. Bitekenova, A.V. Dubolazov and S.Zh. EsirkegenovaKazakh National University, Department of Chemical Physics & Macromolecular Chemistry, Karasai Batyra 95, 480012 Almaty, Kazakhstan khutor@nursat.kz
(Received 29 April 2002 and Received in final form 24 June 2002 Published online: 21 January 2003 )
Abstract
The critical pH values for hydrogen-bonded interpolymer complexes of
poly(N-vinylpyrrolidone) and poly(acrylic acid) in aqueous solutions were
determined. The effect of polymer concentrations, molecular weights and addition
of inorganic salts (NaCl and KCl) on the complexation was studied.
81.05.Lg - Polymers and plastics; rubber; synthetic and natural fibers; organometallic and organic materials.
82.70.Gg - Gels and sols.
83.80.-k - Material type.
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag 2003
