DOI: 10.1140/epje/i2002-10078-0
Complex dynamics in gelling systems
L. de Arcangelis1, 2, E. Del Gado3, 2 and A. Coniglio3, 21 Dipartimento di Ingegneria dell'Informazione, Seconda Università di Napoli, Via Roma 29, 81031 Aversa (CE), Italy
2 INFM Udr di Napoli and Gruppo coordinato SUN, Napoli, Italy
3 Dipartimento di Scienze Fisiche, Università di Napoli "Federico II", Complesso Universitario di Monte Sant'Angelo, 80126 Napoli, Italy
lucilla.dearcangelis@na.infn.it
(Received 10 March 2002 and Received in final form 30 April 2002 / Published online: 23 December 2002)
Abstract
We study the viscoelastic properties and the relaxation process in a
gelling system by means of a minimal statistical-mechanics model. The
model is based on percolation and bond fluctuation dynamics. The
values for the critical exponents of the viscosity and elasticity
agree with a part of the experimental observations and of the
theoretical predictions. The obtained relaxation patterns well
reproduce the behaviour observed in different gelling systems.
05.20.-y - Classical statistical mechanics.
82.70.Gg - Gels and sols.
47.53.+n - Fractals.
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag 2002