https://doi.org/10.1140/epje/s10189-025-00548-6
Regular Article - Flowing Matter
Dielectric spectroscopy of emulsified high-density amorphous ice: the emulsion effect on the dielectric spectrum
1
Department of Physics, Tokai University, 259-1292, Hiratsuka, Kanagawa, Japan
2
Micro Nano Technology Center, Tokai University, 259-1292, Hiratsuka, Kanagawa, Japan
a
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Received:
4
April
2025
Accepted:
15
December
2025
Published online:
6
February
2026
Abstract
Dielectric spectroscopy measurements of bulk and emulsified high-density amorphous ices (HDA) at 1.0 GPa were carried out to examine the effect of emulsion matrix on the dielectric spectra. The presence of emulsion matrix induces the shifts of the loss peak to higher frequency side. The degree of shift depends on the volume fraction of the emulsion matrix to HDA. This indicates that the relaxation time obtained from the dielectric spectra of emulsified HDA is underestimated than the true relaxation time of HDA. The results suggest that the emulsified sample is not appropriate for dielectric spectroscopy measurement in water polyamorphism study, although the emulsification is effective, for example, in avoiding water crystallization.
Supplementary Information The online version contains supplementary material available at https://doi.org/10.1140/epje/s10189-025-00548-6
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© The Author(s), under exclusive licence to EDP Sciences, SIF and Springer-Verlag GmbH Germany, part of Springer Nature 2026
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

