2011 Impact factor 1.944
EPJ E - Soft Matter and Biological Physics
Soft Matter and Biological Physics
Eur. Phys. J. E 16, 77-80 (2005)
DOI: 10.1140/epje/e2005-00009-x

Non-equilibrium behavior of sticky colloidal particles: beads, clusters and gels

H. Sedgwick1, K. Kroy1, 2, A. Salonen1, M.B. Robertson1, S.U. Egelhaaf1 and W.C.K. Poon1

1  School of Physics, The University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ, Scotland, UK
2  Hahn-Meitner-Institut Berlin, Glienicker Str. 100, 14109 Berlin, Germany

w.poon@ed.ac.uk

(Received 17 November 2004 / Published online 31 January 2005)

Abstract
To understand the non-equilibrium behavior of colloidal particles with short-range attraction, we studied salt-induced aggregation of lysozyme. Optical microscopy revealed four regimes: bicontinuous texture, `beads', large aggregates, and transient gelation. The interaction of a metastable liquid-liquid binodal and an ergodic to non-ergodic transition boundary inside the equilibrium crystallization region can explain our findings.

PACS
82.70.Dd - Colloids.
87.15.Nn - Properties of solutions; aggregation and crystallization of macromolecules.

© EDP Sciences, Società Italiana di Fisica, Springer-Verlag 2005